Naming Simple Alkanes

The naming of simple alkanes is a simple matter. The naming of complex alkanes is a complex matter. We will restrict our concerns to the former.

I suspect the main difficulty in this process is the same as in map making - you are really presenting a three dimensional object on a two dimensional surface. It will be quite useful to avail yourself of a standard molecular model kit, if you can find one.

Bearing that in mind, the simplest alkane is methane, which has the molecular formula CH4. Next is ethane, with the formula C2H6. Then propane, C3H8 and butane, C4H10. And so forth.

Alkanes have the generic formula CnH(2n+2), as you can see in the table of the first ten alkanes below.

Number of carbons in chain

Formula for alkane

Formula for branch

name

1

CH4

-CH3

methyl as in methane

2

C2H6

-CH2-CH3

ethyl as in ethane

3

C3H8

-CH2-CH2-CH3

propyl as in propane

4

C4H10

-CH2-CH2-CH2-CH3

butyl as in butane

5

C5H12

-CH2-CH2-CH2-CH2-CH3

pentyl as in pentane

6

C6H14

(-CH2-)5-CH3

hexyl as in hexane

7

C7H16

(-CH2-)6-CH3

heptyl as in heptane

8

C8H18

(-CH2-)7-CH3

octyl as in octane

9

C9H20

(-CH2-)8-CH3

nonyl as in nonane

10

C10H22

(-CH2-)9-CH3

decyl as in decane

 

Next: Drawing Simple Alkanes

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